Confinement stabilises single crystal vaterite rods.
نویسندگان
چکیده
Single-crystals of vaterite, the least-stable anhydrous polymorph of CaCO3, are rare in biogenic and synthetic systems. We here describe the synthesis of high aspect ratio single crystal vaterite rods under additive-free conditions by precipitating CaCO3 within the cylindrical pores of track-etch membranes.
منابع مشابه
Vaterite crystals contain two interspersed crystal structures.
Calcite, aragonite, and vaterite are the three anhydrous polymorphs of calcium carbonate, in order of decreasing thermodynamic stability. Although vaterite is not commonly found in geological settings, it is an important precursor in several carbonate-forming systems and can be found in biological settings. Because of difficulties in obtaining large, pure, single crystals, the crystal structure...
متن کاملNumerical Analysis of Index-Guiding Photonic Crystal Fibers with Low Confinement Loss and Ultra-Flattened Dispersion by FDFD Method
In this article, perfectly matched layer (PML) for the boundary treatment and an efficient compact two dimensional finite-difference frequency-domain (2-D FDFD) method were combined to model photonic crystal fibers (PCF). For photonic crystal fibers, if we assume that the propagation constant along the propagation direction is fixed, three-dimensional hybrid guided modes can be calculated by us...
متن کاملDesign of Single Mode Photonic Crystal Fiber with Outstanding Characteristics of Confinement Loss and Chromatic Dispersion over S to L Communication Band
In this article, a novel structure of photonic crystal fiber with nearly zero ultra-flattened chromatic dispersion and ultra-low confinement loss is presented. By replacing the circular air-holes of two first rings with the elliptical air-holes, a fiber with outstanding features of chromatic dispersion and confinement loss is designed. The proposed structure is optimized for operating in a wide...
متن کاملDesign of Endlessly Single Mode Photonic Crystal Fibers with Desirable Properties using HC-EDA Algorithm
In this article, Hill Climbing (HC) and Estimation of Distribution Algorithm (EDA) are integrated to produce a hybrid intelligent algorithm for design of endlessly Single Mode Photonic Crystal Fibers (SMPCFs) structure with desired properties over the C communication band. In order to analyzing the fiber components, Finite Difference Frequency Domain (FDFD) solver is applied. In addition, a spe...
متن کاملElectric Field-Controlled Crystallizing CaCO3 Nanostructures from Solution.
The role of electric field is investigated in determining the structure, morphology, and crystallographic characteristics of CaCO3 nanostructures crystallized from solution. It is found that the lattice structure and crystalline morphology of CaCO3 can be tailed by the electric field applied to the solution during its crystallization. The calcite structure with cubic-like morphology can be obta...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 50 36 شماره
صفحات -
تاریخ انتشار 2014